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Mineralogy and geochemistry of platinum group elements in the Aguablanca Ni-Cu deposit (SW Spain)

Piña García, Rubén and Gervilla, Fernando and Ortega Menor, Lorena and Lunar, R. (2007) Mineralogy and geochemistry of platinum group elements in the Aguablanca Ni-Cu deposit (SW Spain). Mineralogy and petrology, 92 . pp. 259-282. ISSN 0930-0708

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Official URL: http://www.springer.com/journal/710

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Abstract

The Aguablanca Ni-Cu-(PGE) magmatic sulphide deposit is associated with a magmatic breccia located in the northern part of the Aguablanca gabbro (SW, Iberia). Three types of ores are present: semi-massive, disseminated, and chalcopyrite-rich veined ore. The principal ore minerals are pyrrhotite, pentlandite and chalcopyrite. A relatively abundant platinum-group mineral (PGM) assemblage is present and includes merenskyite, melonite, michenerite, moncheite and sperrylite. Moreover, concentrations of base and precious metals and micro-PIXE analyses were obtained for the three ore-types. The mineralogy and the mantlenormalised chalcophile element profiles strongly suggest that semi-massive ore represents mss crystallisation, whereas the disseminated ore represents an unfractionated sulphide liquid and the chalcopyrite-rich veined ore a Cu-rich sulphide liquid. Palladium-bearing minerals occur commonly enclosed within sulphides, indicating a magmatic origin rather than hydrothermal. The occurrences and the composition of these minerals suggest that Pd was initially dissolved in the sulphides and subsequently exsolved at low temperatures to form bismutotellurides. Negative Pt and Au anomalies in the mantle-normalised chalcophile element profiles, a lack of Cu-S correlation and textural observations (such as sperrylite losing its euhedral shape when in contact with altered minerals) suggest partial remobilisation of Pt, Au and Cu by postmagmatic hydrothermal fluids after the sulphide crystallisation.

Item Type:Article
Additional Information:The original publication is available at www.springerlink.com
Uncontrolled Keywords:Platinum group elements; Aguablanca (Badajoz); Ni-Cu deposits; Spain
Subjects:Sciences > Geology > Crystallography
Sciences > Geology > Mineralogy
ID Code:12272
Deposited On:21 Feb 2011 12:15
Last Modified:07 Nov 2012 14:08

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