Universidad Complutense de Madrid
E-Prints Complutense

Controlling Vilsmeier-Haack processes in meso-methylBODIPYs: A new way to modulate finely photophysical properties in boron dipyrromethenes

Impacto

Descargas

Último año

Palao Utiel, Eduardo y Montalvillo Jiménez, Laura y Esnal Martínez, Ixone y Prieto Montero, Ruth y Rodríguez Agarrabeitia, Antonia R y García Moreno, Inmaculada y Bañuelos Prieto, Jorge y López Arbeloa, Íñigo María y Moya Cerero, Santiago de la y Ortíz García, María Josefa (2017) Controlling Vilsmeier-Haack processes in meso-methylBODIPYs: A new way to modulate finely photophysical properties in boron dipyrromethenes. Dyes and Pigments, 141 . pp. 286-298. ISSN 0143-7208

[img] PDF
Restringido a Sólo personal autorizado del repositorio

1MB

URL Oficial: https://doi.org/10.1016/j.dyepig.2017.02.030




Resumen

In the herein work we report the fine and selective control of competitive processes when submitting meso-methylBODIPYs to Vilsmeier-Haack reaction conditions. These competitive processes generate BODIPYs with opposed photophysical properties, from highly fluorescent dyes enabling laser emission, to non-fluorescent singlet-oxygen photosensitizers. The synthetic control is exerted on the basis of the structure of the starting BODIPY, as well as the electrophilic character (hard or soft) of the formylating reagent.


Tipo de documento:Artículo
Información Adicional:

Received 10 November 2016, Revised 16 January 2017, Accepted 16 February 2017, Available online 20 February 2017.

Palabras clave:Vilsmeier-Haack; Organic synthesis; BODIPY; Photophysics; Laser dyes; Charge transfer
Materias:Ciencias > Química > Optica
Ciencias > Química > Química orgánica
Código ID:45051
Depositado:10 Oct 2017 08:21
Última Modificación:11 Oct 2017 08:44

Descargas en el último año

Sólo personal del repositorio: página de control del artículo