Publication:
Factors affecting flux and ethanol separation performance in vacuum membrane distillation (VMD)

Loading...
Thumbnail Image
Full text at PDC
Publication Date
2003-03-15
Advisors (or tutors)
Editors
Journal Title
Journal ISSN
Volume Title
Publisher
Elsevier Science BV
Citations
Google Scholar
Research Projects
Organizational Units
Journal Issue
Abstract
Membrane distillation (MD) has a great potential as a concentration process for temperature labile liquids such as fruit juices, etc. Besides water, also aroma compounds will permeate through the membrane depending on their volatility and how the MD process is operated on the permeate side.In this paper, an experimental and theoretical investigation of the influence of concentration polarisation and temperature polarisation on the flux and selectivity of binary aqueous mixtures of ethanol is presented for vacuum membrane distillation (VMD) processes. Experimental results include changes of the following parameters: nature of solutions, membrane material and pore size, feed temperature, recirculation flow rate. One method was proposed in order to evaluate the concentration polarisation effects from the fit of the experimental data. General models taking into account Knudsen and viscous flows were proposed, but viscous contribution resulted to be negligible under our operating conditions. Therefore, theoretical fluxes were estimated using Knudsen model and a good agreement between them and the experimental ones was found.
Description
© 2002 Elsevier Science B.V. Postdoctoral grant from Universidad Complutense of Madrid by M.A. Izquierdo Gil and support from the Danish Directorate for Development are gratefully acknowledged.
UCM subjects
Unesco subjects
Keywords
Citation
[1] K.W. Lawson, D.R. Lloyd, Review: membrane distillation, J. Membr. Sci. 124 (1997) 1. [2] M.A. Izquierdo Gil, M.C. García Payo, C. Fernández Pineda, Direct contact membrane distillation of sugar aqueous solutions, Sep. Sci. Technol. 34 (9) (1999) 1773. [3] M. Khayet, P Godino, J.I. Mengual, Nature of flow on sweeping gas membrane distillation, J. Membr. Sci. 170 (2000) 243. [4] M.A. Izquierdo Gil, M.C. García Payo, C. Fernández Pineda, Air gap membrane distillation of sucrose aqueous solutions, J. Membr. Sci. 155 (1999) 291. [5] S. Bandini, C. Gostoli, G.C. Sarti, Separation efficiency in vacuum membrane distillation, J. Membr. Sci. 73 (1992) 217. [6] S. Bandini, A. Saavedra, G.C. Sarti, Vacuum membrane distillation: experiments and modeling, AIChE J. 43 (2) (1997) 398. [7] G.C. Sarti, C. Gostoli, S. Bandini, Extraction of organic components from aqueous streams by vacuum membrane distillation, J. Membr. Sci. 80 (1993) 21. [8] N. Couffin, C. Cabassud, V. Lahoussine Turcaud, A new process to remove halogenated VOCs for drinking water production: vacuum membrane distillation, Desalination 117 (1998) 233. [9] E.A. Mason, A.P. Malinauskas, Gas Transport in Porous Media: The Dusty-Gas Model, Elsevier, Amsterdam, 1983. [10] E.H. Kennard, Kinetic Theory of Gases, McGraw-Hill, New York, 1938. [11] K.W. Lawson, D.R. Lloyd, Membrane distillation. I. Module design and performance evaluation using vacuum membrane distillation, J. Membr. Sci. 120 (1996) 11. [12] R.W. Schofield, A.G. Fane, C.J.D. Fell, Gas and vapour transport through microporous membranes. I. Knudsen Poiseuille transition, J. Membr. Sci. 53 (1990) 159. [13] R.W. Schofield, A.G. Fane, C.J.D. Fell, Gas and vapour transport through microporous membranes. II. Membrane distillation, J. Membr. Sci. 53 (1990) 173. [14] E.A. Mason, A.P. Malinauskas, R.B. Evans III, Flow and diffusion of gases in porous media, J. Chem. Phys. 46 (8) (1967) 3199. [15] M. Mulder, Basic Principles of Membrane Technology, Kluwer Academic Publishers, Dordrecht, 1991. [16] M.C. Porter, Concentration polarization with membrane ultrafiltration, Ind. Eng. Chem., Prod. Res. Dev. 11 (1972) 234. [17] Handbook of Chemistry and Physics, 55th ed., CRC Press, Boca Raton, 1974–1975. [18] Sonntag, Van Wylen, Introduction to Thermodynamics Classical and Statistical, Wiley, NY, 1991. [19] K.W. Lawson, M.S. Hall, R. Lloyd, Compaction of microporous membranes used in membrane distillation. I. Effect on gas permeability, J. Membr. Sci. 101 (1995) 99. [20] C. Fernández Pineda, M.A. Izquierdo Gil, M.C. García Payo, Gas permeation and direct contact membrane distillation experiments and their analysis using different models, J. Membr. Sci. 198 (2002) 33. [21] J.M. Prausnitz, Molecular Thermodynamics of Fluid Phase Equilibria, Prentice-Hall, Englewood Cliffs, NJ, 1969.
Collections