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A Novel Photoconductive PVK/SiO_2 Interpenetrated Network Prepared by the Sol−Gel Process



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Ramos Zapata, Gonzalo and Belenguer Dávila, Tomás and Monte Muñoz de la Peña, Francisco de and Levy, David and Bernabeu Martínez, Eusebio (2003) A Novel Photoconductive PVK/SiO_2 Interpenetrated Network Prepared by the Sol−Gel Process. Journal Of Physical Chemistry B, 107 (1). pp. 110-112. ISSN 1520-6106

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Official URL: http://dx.doi.org/10.1021/jp026759+



In this work, we describe the preparation of a novel photoconductive sol−gel material based on an organic/inorganic interpenetrating network (IPN). The composition of the sol−gel photoconductive material mimics the well-known polymeric one based on poly(N-vinylcarbazole) (PVK) as the charge-transporting matrix and 2,4,7-trinitro-9-fluorenone (TNF) as the sensitizer. The resulting photoconductive material (PVK/SiO_2 IPN) shows a photosensitivity of 10^-11 cm/(Ω W) in range to that reported for some analogue polymeric compounds and the highest ever reported for hybrid sol−gel materials.

Item Type:Article
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© 2003 American Chemical Society.
The authors are grateful to the CICYT for the research grant MAT 2001-5073-E. Gonzalo Ramos is also grateful to INTA for a Rafael Calvo Rodés fellowship.

Uncontrolled Keywords:Photorefractive Polymer, Photogeneration, Composites, Transport
Subjects:Sciences > Physics > Optics
ID Code:26762
Deposited On:25 Sep 2014 10:48
Last Modified:25 Sep 2014 10:48

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