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Reaction of diazocompounds with C70: unprecedented synthesis and characterization of isomeric [5,6]-fulleroids†

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Vidal, Sara and Izquierdo, Marta and Filippone, Salvatore and Brunetti, Fulvio G. and Martín, Nazario (2015) Reaction of diazocompounds with C70: unprecedented synthesis and characterization of isomeric [5,6]-fulleroids†. Chemical Communications (Cambridge), 51 (94). pp. 16774-16777. ISSN 1364-548x(Online) , 1359-7345 (print)

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Official URL: http://pubs.rsc.org/en/content/articlepdf/2015/cc/c5cc07602a



Abstract

The synthesis of a variety of PCBM-type [5,6]-fulleroids and their further highly selective photoisomerization to the respective [6,6]-methanofullerenes is presented. Interestingly, the chemical reactivity of [5,6]-fulleroids reveals the same trend (a 4 b 4 c 4 d) to that
observed for pristine C70 (a 4 b 4 c 4 d).


Item Type:Article
Uncontrolled Keywords:isomerization; synthesis
Subjects:Sciences > Chemistry > Chemistry, Organic
ID Code:35961
Deposited On:26 Feb 2016 09:24
Last Modified:02 Mar 2016 15:26

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