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Cyclobuteno[60]fullerenes as efficient n-type organic semiconductors

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Reboredo, Silvia and Girón, Rosa M. and Filippone, Salvatore and Mikie, Tsubasa and Sakurai, Tsuneaki and Seki, Shu and Martín, Nazario (2016) Cyclobuteno[60]fullerenes as efficient n-type organic semiconductors. Chemistry: a european journal, 22 (38). pp. 13627-13631. ISSN 0947-6539

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/chem.201602813/abstract



Abstract

Cyclobuteno[3,4:1,2][60]fullerenes have been prepared in a straightforward manner by a simple reaction between [60]fullerene and readily available allenoates or alkynoates as organic reagents under basic and mild conditions. The chemical structure of the new modified fullerenes has been determined by standard spectroscopic techniques and confirmed by X-Ray diffraction analysis. Some of these new fullerene derivatives exhibit a remarkable intrinsic electron mobility – determined by using flash-photolysis time-resolved microwave conductivity (FP-TRMC) measurements – which surpasses that of the well-known PCBM, thus behavi ng as promising n-type organic semiconductors.


Item Type:Article
Uncontrolled Keywords:alkynoates; allenoates; cyclobutene; electron mobility; fullerenes
Subjects:Sciences > Chemistry > Chemistry, Organic
ID Code:41715
Deposited On:07 Mar 2017 17:04
Last Modified:01 Oct 2017 23:01

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