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Stereodivergent-at-Metal Synthesis of [60]Fullerene Hybrids

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Marco Martínez, Juan and Vidal, Sara and Fernández, Israel and Filippone, Salvatore and Martín, Nazario (2017) Stereodivergent-at-Metal Synthesis of [60]Fullerene Hybrids. Angewandte Chemie, 56 (8). pp. 2136-2139. ISSN 1433-7851

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/ange.201611475/full



Abstract

Chiral fullerene–metal hybrids with complete control over the four stereogenic centers, including the absolute configuration of the metal atom, have been synthesized for the first time. The stereochemistry of the four chiral centers formed during [60]fullerene functionalization is the result of both the chiral catalysts employed and the diastereoselective addition of the metal complexes used (iridium, rhodium, or ruthenium).DFT calculations underpin the observed configurational stability at the metal center, which does not undergo an epimerization process.


Item Type:Article
Uncontrolled Keywords:chiral metallofullerenes · chiral-at-metal complexes · enantioselective synthesis · fullerene chemistry
Subjects:Sciences > Chemistry > Chemistry, Organic
ID Code:41719
Deposited On:08 Mar 2017 09:11
Last Modified:13 Feb 2018 00:01

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