Universidad Complutense de Madrid
E-Prints Complutense

Cyclooctyne [60]fullerene hexakis adducts: a globular scaffold for copper-free click chemistry

Impacto

Downloads

Downloads per month over past year



Ramos, Soriano and Reina, José J. and Pérez, Sánchez and Illescas, Beatriz M. and Rojo, Javier and Martín, Nazario (2016) Cyclooctyne [60]fullerene hexakis adducts: a globular scaffold for copper-free click chemistry. Chemical Communications, 52 (69). pp. 10544-10546. ISSN 1359-7345

[img]
Preview
PDF
255kB

Official URL: http://pubs.rsc.org/en/content/articlepdf/2016/cc/c6cc05484f



Abstract

The synthesis of a new highly symmetric hexakis adduct of C60 appended with 12 cyclooctyne moieties has been carried out. This compound has been used for the copper-free strain-promoted cycloaddition reaction to a series of azides with excellent yields.This strategy for the obtention of clicked adducts of [60]fullerene is of special interest for biological applications.


Item Type:Article
Subjects:Sciences > Chemistry > Chemistry, Organic
ID Code:41722
Deposited On:08 Mar 2017 10:15
Last Modified:01 Aug 2017 23:01

Origin of downloads

Repository Staff Only: item control page