Publication: Cyclooctyne [60]fullerene hexakis adducts: a
globular scaffold for copper-free click chemistry
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Publication Date
2016-07
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RSC
Abstract
The synthesis of a new highly symmetric hexakis adduct of C60 appended with 12 cyclooctyne moieties has been carried out. This compound has been used for the copper-free strain-promoted cycloaddition reaction to a series of azides with excellent yields.This strategy for the obtention of clicked adducts of [60]fullerene is of special interest for biological applications.