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Preparation of dipyrrins from F-BODIPYs by treatment with methanesulfonic acids

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Abstract
An alternative metal-free soft procedure for the preparation of dipyrrins from F-BODIPYs is reported. The new method makes possible to obtain certain dipyrrin derivatives that were unaccessible from F-BODIPYs to date. To demonstrate the ability of the new procedure, dipyrrins having highly reactive groups, such as chloro, cyano or acetoxyl, have been easily obtained from the corresponding F-BODIPY, which shows the synthetic utility of the reported methodology.
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The article was received on 27 Jul 2015, accepted on 03 Aug 2015 and first published on 03 Aug 2015
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