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Effect of Incarcerated HF on the Exohedral Chemical Reactivity of HF@C60

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Vidal, Sara and Izquierdo, Marta and Alom, Shamim and García-Borrás, Marc and Filippone, Salvatore and Osuna, Silvia and Solà, Miquel and Whitby, Richard J. and Martin León, Nazario (2017) Effect of Incarcerated HF on the Exohedral Chemical Reactivity of HF@C60. Chemical Communications, 53 (80). pp. 10965-11100. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlepdf/2017/cc/c7cc05987f



Abstract

The first chemical modification on the brand new endohedral HF@C60 is reported. In particular, the isomerization from optically pure (2S,5S)-cis-pyrrolidino[3,4:1,2][60]fullerene 2b to (2S,5R)-trans-pyrrolidino[3,4:1,2][60]fullerene 2b has been studied and compared with empty C60 (2a) and endohedral H2O@C60 (3). The comparative study shows a kinetic order for the isomerization process of H2O@C60 ˃ HF@C60 ˃ C60, thus confirming the effect of the incarcerated species on the zwitterionic intermediate stability.


Item Type:Article
Subjects:Sciences > Chemistry > Chemistry, Organic
ID Code:46345
Deposited On:06 Feb 2018 11:52
Last Modified:14 Oct 2018 23:01

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