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Enantiomer-Specific Oriented Attachment of Guanidine Carbonate Crystals

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Sivakumar, Reajean and Kwiatoszynski, Julien and Fouret, Amaury and Nguyen, Thi Phuong Thao and Ramrup, Parsram and Cheung, Pui Shan Monica and Cintas, Pedro and Viedma Molero, Cristóbal and Cuccia, Louis A. (2016) Enantiomer-Specific Oriented Attachment of Guanidine Carbonate Crystals. Crystal Growth and Design, 16 (7). pp. 3573-3576. ISSN Issn 1528-7483 ; Essn 1528-7505)

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Official URL: https://pubs.acs.org/toc/cgdefu/16/7


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Abstract

Oriented attachment, a non-classical crystallization phenomenon, describes the spontaneous self-assembly of adjoining crystals with common crystallographic orientations. Introducing chiral recognition between crystals during oriented attachment enables enantiomer-specificity and the formation of homochiral structures. Herein, we report efficient enantiomer-specific oriented attachment for suspended crystals of guanidine carbonate to form mesoscale homochiral or enantioenriched aggregates under boiling or shaking conditions. These aggregates display polyhedral macrostructures and their chirality was monitored using circular dichroism and polarized light microscopy.


Item Type:Article
Subjects:Sciences > Geology > Crystallography
Sciences > Geology > Stratigraphic geology
ID Code:57805
Deposited On:19 Nov 2019 11:54
Last Modified:19 Nov 2019 11:54

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