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Frame-invariant Fick diffusion matrices of multicomponent fluid mixtures

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Ortiz de Zárate Leira, José María and Sengers, Jan V. (2020) Frame-invariant Fick diffusion matrices of multicomponent fluid mixtures. Physical chemistry chemical physics, 22 (31). pp. 17597-17604. ISSN 1463-9076

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Official URL: https://doi.org/10.1039/d0cp01110j


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Abstract

Extension of a description of mass diffusion in binary fluids based on Fick's law to multicomponent fluids requires introduction of diffusion matrices. A problem is that Fick diffusion matrices commonly adopted for multicomponent fluids depend on the velocity frame of reference. In this paper we show how one can define Fick diffusion matrices for multicomponent fluids that are frame invariant.


Item Type:Article
Additional Information:

We thank Aliaksandr Mialdun from the Universite Libre de Bruxelles for a careful review of the manuscript. We also thank Dick Bedeaux of the Norwegian University of Science and Technology in Trondheim for valuable discussions. We acknowledge support from the European Space Agency (ESA) through the TechNEs MAP project. The research at the Complutense University was further supported by grant ESP2017-83544-C3-2-P of the Spanish Agencia Estatal de Investigación.

Uncontrolled Keywords:Ternary mixtures; Coefficients; Binary
Subjects:Sciences > Physics > Thermodynamics
ID Code:62097
Deposited On:23 Sep 2020 10:02
Last Modified:23 Sep 2020 11:00

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