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A note on the dissolution of spherical crystals

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2001-04
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Cambridge University Press
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We consider here the radial Stefan problem with Gibbs-Thomson law, which is a classical model describing growth or melting of a spherical crystal in a surrounding liquid. We shall specialize to the cases of two and three space dimensions and discuss the asymptotic behaviour of a melting crystal near its dissolution time t(*)>0. We prove here that, when the interface shrinks monotonically, the asymptotics near t=t(*) is of the form R(t)~(3σ(t(*)-t))(1/3), u(r,t)~-σ/r for r~R(t), r>R(t). Here, R(t) denotes the radius of the crystal, σ is a surface tension parameter and u(r,t) represents the field temperature. An important point to be noticed is that (*) exhibits no dependence on the space dimension N, in sharp contrast with results known for the case σ = 0.
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M. Abramowitz and I. A. Stegun. Handbook of mathematical functions (New York: Dover, 1970). B. Caroli, C. Caroli and B. Roulet. Instabilities of planar solidification fronts. In Solids far from equilibrium (ed. C. Godrèche), pp. 155–296. (Cambridge University Press, 1992). A. Friedman. Partial differential equations of parabolic type (Malabar, FL: Robert Krieger, 1983). M. A. Herrero and J. J. L. Velázquez. On the melting of ice balls. SIAM J. Math. Analysis 28 (1997), 1–32. O. A. Ladyzenskaja, V. A. Solonnikov and N. N. Uraltseva. Linear and quasilinear equations of parabolic type, Transl. Mathematical Monographs, vol. 23 (Providence, RI: American Mathematical Society, 1968). D. G. Schaeffer. A new proof of the infinite differentiability of the solution of the free boundary in the Stefan problem. J. Diff. Eqns 20 (1976), 266–269. B. Sherman. A general one-phase Stefan problem. Q. Appl. Math. 28 (1970), 377–383.
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