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Electroosmotic transport through a cation-exchange membrane: Effect of the stirring on the dependence of the electroosmotic permeability on the temperature

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1999-04-01
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Academic Press Inc Elsevier Science
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The electroosmotic flux through a cation-exchange membrane has been obtained in different situations. From these measurements, the apparent electroosmotic permeability, W, of a cation-exchange membrane has been determined as a function of the temperature, T, and the stirring rate, v, of the solutions. In all the experimental situations studied, W decreases when v increases, while it can increase or decrease with T depending on the temperature range considered. For this last reason, the (T,W) curves show a minimum whose value and position depend on the experimental conditions established. The influence of the concentration polarization effect in the value of W and in its dependence with v and T is studied and quantified.
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© 1999 by Academic Press
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1. Mackay, D., and Meares, P., Trans. Faraday Soc. 55, 1221 (1959). 2. Carr, C. W., McClintock, R., and Sollner, K., J. Electrochem. Soc. 109, 251 (1062). 3. Laksminarayanaiah, N., and Subrahmanyan, V., J. Phys. Chem. 72, 1253 (1968). 4. Laksminarayanaiah, N., J. Electrochem. Soc. 116, 338 (1969). 5. Pefferkorn, E. Schmitt, A., Varoqui, R., J. Membrane Sci. 4, 17 (1978). 6. Tasaka, M., Tamura, S.,Takemura, N., and Morimoto, K., J. Membrane Sci. 12, 169 (1982). 7. Haase, R., and Harff, K., J. Membrane Sci. 12, 279 (1983). 8. Narebska, A, Kujawski, W, and Kotter, S., J. Membrane Sci. 30, 125 (1987). 9. Rastogi, R. P., and Jha, K. M., J. Phys. Chem. 70, 1017 (1966). 10. George, J. K. B., and Courant, R. A., J. Phys. Chem. 71, 246 (1967). 11. Barragán, V. M., and Ruiz Bauzá, C., J. Colloid Interface Sci. 194, 114 (1997). 12. Barragán, V. M., Ruiz-Bauzá, C., and Mengual, J. I., J. Colloid Interface Sci. 168, 458 (1994). 13. Katchalsky, T. G., and Curran, P. F., “Nonequilibrium Thermodynamics in Biophysics.” Harvard University Press, Harvard, MA, 1967. 14. Helfferich, F., “Ion-Exchange.” McGraw-Hill, New York, 1962. 15. Bockris, J., and Reddy, A., “Modern Electrochemistry.” Plenum/Rosseta, New York, 1973. 16. Schmid, G., Z. Elektrochem. 54, 424 (1950). 17. Schmid, G., Z. Elektrochem. 55, 229 (1951). 18. Schmid, G., Z. Elektrochem. 56, 181 (1952). 19. Schmid, G., Chem.-Ing-Tech. 37, 616 (1965). 20. Riande, E., in “Physics of Electrolytes” (J. Hladik, Ed.), p. 486. Academic Press, London, 1972. 21. Vink, M., Arkiv. Kem. 19, 15 (1961). 22. Belluci, F. Drioli, F. S., Gaeta, N., Mita, D. G., Paglicua, N., and Tomadacis, D., J. Membrane Sci. 7, 169 (1980). 23. Barragán, V. M., Rueda, C., and Ruiz-Bauzá, C., J. Colloid Interface Sci. 172, 361 (1995). 24. Barragán, V. M., Ruiz-Bauzá, C., and Mengual, J. I., J. Membrane Sci. 95, 1 (1994). 25. Barragán, V. M., and Ruiz Bauzá, C., J. Colloid Interface Sci., in press. 26. Mengual, J. I., and García-López, F., J. Membrane Sci. 26, 11 (1986).
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