Publication: Thermal growth and luminescence of wurtzite ZnS nanowires and nanoribbons
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2012-06-01
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Elsevier Science B.V.
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ZnS nanowires and nanoribbons have been obtained by the vapor–solid (VS) method. The morphology depends mainly on the deposition temperature; nanowires are grown at temperatures between 300 °C and 650 °C while the growth of nanoribbons takes place at deposition temperatures in the range 650 °C–900 °C. X-ray diffraction (XRD) and transmission electron microscopy (TEM) studies show that from cubic ZnS precursor hexagonal-phase nanostructures are obtained. Cathodoluminescence (CL) and photoluminescence (PL) measurements show a dominance of the native defects related emission compared to the near band edge emission, with marked differences between nanowires and nanoribbons.
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©2012 Elsevier B.V.
This work was supported by MICINN (Projects MAT2009-07882 and CSD2009-0013). B. Sotillo acknowledges Ministerio de Educación (Subprograma FPU) of Spain for financial support.
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