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Mialdun, A. and Sechenyh, V. and Legros, J. C. and Ortiz de Zárate Leira, José María and Shevtsova, V. (2013) Investigation of Fickian diffusion in the ternary mixture of 1,2,3,4-tetrahydronaphthalene, isobutylbenzene, and dodecane. Journal of Chemical Physics, 139 (10). ISSN 0021-9606
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Official URL: http://dx.doi.org/10.1063/1.4820357
Abstract
We present a comprehensive analysis of experimental results obtained for Fickian diffusion in the benchmark ternary liquid mixture of 1,2,3,4-tetrahydronaphthalene, isobutylbenzene, and dodecane (nC(12)) with equal mass fractions. Isothermal diffusion coefficients have been measured by two independent experimental methods: by Taylor dispersion technique, and by a counter flow cell fitted with an optical interferometry device. The experimental diffusion matrices have been critically analyzed regarding the Onsager reciprocal relations, for which we introduce a matrix asymmetry index S-2 that is independent of the frame of reference and the component order.
| Item Type: | Article |
|---|---|
| Additional Information: | © 2013 AIP Publishing LLC. This work is supported by the PRODEX programme of the Belgian Federal Science Policy Office, ESA. The authors would like to thank referee for useful discussion of the fitting algorithms. |
| Uncontrolled Keywords: | Taylor dispersion technique; Optical-properties; Light-scattering; Liquid-mixtures; Coefficients; Binary; Interferometry; Cyclohexane; Methanol; Toluene |
| Subjects: | Sciences > Physics > Thermodynamics |
| ID Code: | 27267 |
| Deposited On: | 05 Nov 2014 09:07 |
| Last Modified: | 26 Feb 2015 15:30 |
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