¡Nos trasladamos! E-Prints cerrará el 7 de junio.

En las próximas semanas vamos a migrar nuestro repositorio a una nueva plataforma con muchas funcionalidades nuevas. En esta migración las fechas clave del proceso son las siguientes:

7 de junio: congelación de E-Prints. A partir de este momento, no se podrá hacer ningún depósito ni cambio, modificación o edición.
12 al 30 de junio: migración de E-Prints a Docta Complutense, comprobación y visto bueno de la migración
3 de julio: entrada en producción de Docta Complutense

Es muy importante que cualquier depósito se realice en E-Prints Complutense antes del 7 de junio. En caso de urgencia para realizar un depósito, se puede comunicar a docta@ucm.es.

Spanish | Contactar

Electronic excitation of furfural as probed by high-resolution vacuum ultraviolet spectroscopy, electron energy loss spectroscopy, and ab initio calculations

Impacto

Downloads

Downloads per month over past year

View download statistics for this eprint

Altmetric

>> Ir a Scopus

Buscar en Google Scholar™

Blanco Ramos, Francisco (2015) Electronic excitation of furfural as probed by high-resolution vacuum ultraviolet spectroscopy, electron energy loss spectroscopy, and ab initio calculations. Journal of Chemical Physics, 143 (14). ISSN 0021-9606

[thumbnail of Blanco Ramos F 05 LIBRE.pdf]

Preview

PDF
1MB

Official URL: http://dx.doi.org/10.1063/1.4932603

Publisher

==>>> Export to other formats

Abstract

The electronic spectroscopy of isolated furfural (2-furaldehyde) in the gas phase has been investigated using high-resolution photoabsorption spectroscopy in the 3.5-10.8 eV energy-range, with absolute cross section measurements derived. Electron energy loss spectra are also measured over a range of kinematical conditions. Those energy loss spectra are used to derive differential cross sections and in turn generalised oscillator strengths. These experiments are supported by ab initio calculations in order to assign the excited states of the neutral molecule. The good agreement between the theoretical results and the measurements allows us to provide the first quantitative assignment of the electronic state spectroscopy of furfural over an extended energy range. (C) 2015 AIP Publishing LLC.

Item Type:	Article
Additional Information:	©2015 AIP Publishing LLC Artículo firmado por 18 autores. F.F.S. and P.L.V. acknowledge the Portuguese Foundation for Science and Technology (FCT-MEC) through Grant Nos. SFRH/BPD/68979/2010 and SFRH/BSAB/105792/2014, respectively, the research Grant Nos. PTDC/FIS-ATO/1832/2012 and UID/FIS/00068/2013. P.L.V. also acknowledges his Visiting Research Fellow position at Flinders University, Adelaide, South Australia. The Patrimoine of the University of Liege, the Fonds National de la Recherche Scientifique, and the Fonds de la Recherche Fondamentale Collective of Belgium have also supported this research. E.L. and R.F.C.N. thank CNPq (Brazil) and the Science Without Borders Programme for opportunities to study abroad. The authors wish to acknowledge the beam time at the ISA synchrotron at Aarhus University, Denmark. The research leading to these results has received funding from the European Community's Seventh Framework Programme (Grant No. FP7/2007-2013) CALIPSO under Grant Agreement No. 312284. D.B.J. thanks the Australian Research Council for financial support provided through a Discovery Early Career Research Award. M.J.B. also thanks the Australian Research Council for some financial support, while M.J.B. and M.C.A.L. acknowledge the Brazilian agencies CNPq and FAPEMIG for financial support. F.B. and G.G. acknowledge partial financial support from the Spanish Ministry MINECO (Project No. FIS2012-31230) and the EU COST Action No. CM1301 (CELINA). Finally, R.F.C., M.T.do N.V., M.H.F.B., and M.A.P.L. acknowledge support from the Brazilian agency CNPq.
Uncontrolled Keywords:	Beam irradiation pretreatment; Differential cross-sections; Enzymatic-hydrolysis; 2-furaldehyde vapor; Vuv photoabsorption; Absorption; Biofuels; States; Photochemistry; Transition.
Subjects:	Sciences > Physics > Nuclear physics
ID Code:	34848
Deposited On:	16 Dec 2015 16:55
Last Modified:	10 Dec 2018 14:57

Origin of downloads

Repository Staff Only: item control page