Impacto
Downloads
Downloads per month over past year
Palao Utiel, Eduardo and Montalvillo Jiménez, Laura and Esnal Martínez, Ixone and Prieto Montero, Ruth and Rodríguez Agarrabeitia, Antonia R and García Moreno, Inmaculada and Bañuelos Prieto, Jorge and López Arbeloa, Íñigo María and Moya Cerero, Santiago de la and Ortíz García, María Josefa (2017) Controlling Vilsmeier-Haack processes in meso-methylBODIPYs: A new way to modulate finely photophysical properties in boron dipyrromethenes. Dyes and Pigments, 141 . pp. 286-298. ISSN 0143-7208
![[thumbnail of agarrabeitia_controlling vilsmeier-Elsevier-2017.pdf]](/style/images/fileicons/application_pdf.png) |
PDF
Restringido a Repository staff only 1MB |
Official URL: https://doi.org/10.1016/j.dyepig.2017.02.030
Abstract
In the herein work we report the fine and selective control of competitive processes when submitting meso-methylBODIPYs to Vilsmeier-Haack reaction conditions. These competitive processes generate BODIPYs with opposed photophysical properties, from highly fluorescent dyes enabling laser emission, to non-fluorescent singlet-oxygen photosensitizers. The synthetic control is exerted on the basis of the structure of the starting BODIPY, as well as the electrophilic character (hard or soft) of the formylating reagent.
| Item Type: | Article |
|---|---|
| Additional Information: | Received 10 November 2016, Revised 16 January 2017, Accepted 16 February 2017, Available online 20 February 2017. |
| Uncontrolled Keywords: | Vilsmeier-Haack; Organic synthesis; BODIPY; Photophysics; Laser dyes; Charge transfer |
| Subjects: | Sciences > Chemistry > Optics Sciences > Chemistry > Chemistry, Organic |
| ID Code: | 45051 |
| Deposited On: | 10 Oct 2017 08:21 |
| Last Modified: | 11 Oct 2017 08:44 |
Origin of downloads
Repository Staff Only: item control page
