Publication:
Effect of Incarcerated HF on the Exohedral Chemical Reactivity of HF@C60

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Publication Date
2017-10-14
Authors
Vidal, Sara
Izquierdo, Marta
Alom, Shamim
García-Borrás, Marc
Osuna, Silvia
Solà, Miquel
Whitby, Richard J.
Martin León, Nazario
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The first chemical modification on the brand new endohedral HF@C60 is reported. In particular, the isomerization from optically pure (2S,5S)-cis-pyrrolidino[3,4:1,2][60]fullerene 2b to (2S,5R)-trans-pyrrolidino[3,4:1,2][60]fullerene 2b has been studied and compared with empty C60 (2a) and endohedral H2O@C60 (3). The comparative study shows a kinetic order for the isomerization process of H2O@C60 ˃ HF@C60 ˃ C60, thus confirming the effect of the incarcerated species on the zwitterionic intermediate stability.
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