New Fe2O3-Clay@C Nanocomposite Anodes for Li-Ion Batteries Obtained by Facile Hydrothermal Processes



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Alonso Domínguez, Daniel and Pico, María and Álvarez Serrano, Inmaculada and López García, María Luisa (2018) New Fe2O3-Clay@C Nanocomposite Anodes for Li-Ion Batteries Obtained by Facile Hydrothermal Processes. Nanomaterials, 8 (10). p. 808. ISSN 2079-4991

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New iron-oxide-based anodes are prepared by an environmentally-friendly and low-cost route. The analysis of the composition, structure, and microstructure of the samples reveals the presence of a major hematite phase, which is accompanied by a certain concentration of an oxyhydroxide phase, which can act as a “lithium-reservoir”. By using sodium alginate as a binder, the synthesized anodes display superior electrochemical response, i.e., high specific capacity values and high stability, not only versus Li but also versus a high voltage cathode in a full cell. From these bare materials, clay-supported anodes are further obtained using sepiolite and bentonite natural silicates. The electrochemical performance of such composites is improved, especially for the sepiolite-containing one treated at 400 °C. The thermal treatment at this temperature provides the optimal conditions for a synergic nano-architecture to develop between the clay and the hematite nanoparticles. High capacity values of ~2500 mA h g−1 after 30 cycles at 1 A g−1 and retentions close to 92% are obtained. Moreover, after 450 cycles at 2 A g−1 current rate, this composite electrode displays values as high as ~700 mA h g−1. These results are interpreted taking into account the interactions between the iron oxide nanoparticles and the sepiolite surface through hydrogen bonds. The electrochemical performance is not only dependent on the oxidation state and particle morphology, but the composition is revealed as a key feature.

Item Type:Article
Uncontrolled Keywords:iron oxide anodes; sepiolite; bentonite; lithium ion battery
Subjects:Sciences > Chemistry > Chemistry, Inorganic
ID Code:66758
Deposited On:19 Jul 2021 14:40
Last Modified:20 Jul 2021 07:16

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