C*-BODIPYs: Exploring a New Strategy to Transfer Chirality towards BODIPY Chiroptics

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Jiménez González, Josué and Sánchez Camacho, Juan and Moreno Jiménez, Florencio and Rodríguez Agarrabeitia, Antonia and Arbeloa, Teresa and Cabreros, Trevor A. and Muller, Gilles and Bañuelos, Jorge and Maroto, Beatriz Lora and Moya Cerero, Santiago de la (2020) C*-BODIPYs: Exploring a New Strategy to Transfer Chirality towards BODIPY Chiroptics. Proceedings, 41 (1). p. 53. ISSN 2504-3900

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Official URL: https://doi.org/10.3390/ecsoc-23-06610




Abstract

C*-BODIPYs, that is, boron dipyrromethenes (BODIPYs) which have chiral carbons attached directly to the boron center, are introduced for the first time. These novel chiral BODIPYs mean a new strategy for the chiral perturbation of the inherently achiral BODIPY chromophore that is directed to enable chiroptical properties. Their preparation is very simple and only implies the complexation of a dipyrrin with an enantiopure dialkylborane having boron bonded to chiral carbons.


Item Type:Article
Uncontrolled Keywords:BODIPYs; circular dichroism; circularly polarized luminescence; CPL-SOMs
Subjects:Sciences > Chemistry > Chemistry, Organic
ID Code:66782
Deposited On:12 Jul 2021 14:11
Last Modified:12 Jul 2021 14:11

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