Solvent-Controlled Switching of Cycloisomerization to Transposition in the Ag/Cu-Promoted Reaction of Terminal α-Allenols

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Toledano Pinedo, Mireia and Anatóliev, Hristo and Martínez del Campo, Teresa and Almendros, Pedro (2019) Solvent-Controlled Switching of Cycloisomerization to Transposition in the Ag/Cu-Promoted Reaction of Terminal α-Allenols. Proceedings, 41 (1). p. 58. ISSN 2504-3900

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Official URL: https://doi.org/10.3390/ecsoc-23-06467




Abstract

We report herein a study on the Ag/Cu-catalyzed reactivity of α-allenols. The focus was the development of new methodologies for cyclization and/or transposition of this moiety. By simple solvent switch, the divergent preparation of dihydrofurans and 3-halo-3-alkenals in a controlled manner has been reached.


Item Type:Article
Uncontrolled Keywords:allene; dihydrofurans and 3-halo-3-alkenals
Subjects:Sciences > Chemistry > Chemistry, Organic
ID Code:66785
Deposited On:12 Jul 2021 14:06
Last Modified:13 Jul 2021 06:42

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