Publication: An N-annulated, rylene-based twistacene as scaffold for long
supramolecular polymers
Loading...
Official URL
Full text at PDC
Publication Date
2022-10-27
Advisors (or tutors)
Editors
Journal Title
Journal ISSN
Volume Title
Publisher
Wiley
Citations
Exportar
Abstract
The multistep synthesis of the N-annulated rylenecarbodiimide 1 is reported. The large p-surface and the operation of a fourfold array of H-bonding interactions between the trialkoxybenzamide units yield highly stable supramolecular polymers, the stability of which has been quantified by applying the denaturation model. The operation of these non-covalent interactions affords long 1D-supramolecular polymers that have been visualized by atomic force microscopy (AFM).
Description
CRUE-CSIC (Acuerdos Transformativos 2022)