Publication: An N-annulated, rylene-based twistacene as scaffold for long
supramolecular polymers
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Publication Date
2022-10-27
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Wiley
Abstract
The multistep synthesis of the N-annulated rylenecarbodiimide 1 is reported. The large p-surface and the operation of a fourfold array of H-bonding interactions between the trialkoxybenzamide units yield highly stable supramolecular polymers, the stability of which has been quantified by applying the denaturation model. The operation of these non-covalent interactions affords long 1D-supramolecular polymers that have been visualized by atomic force microscopy (AFM).
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CRUE-CSIC (Acuerdos Transformativos 2022)